Willemite

Willemite is a zinc silicate mineral (Zn2SiO4) and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a variant in which part of the zinc is partly replaced by manganese, it occurs in solid brown masses.

Willemite
Willemite from Namibia
General
CategorySilicate mineral
Formula
(repeating unit)
Zn2SiO4
IMA symbolWlm
Strunz classification9.AA.05 (10 ed)
8/A.01-20 (8 ed)
Dana classification51.1.1.2
Crystal systemTrigonal
Crystal classRhombohedral (3)
(same H-M symbol)
Space groupR3
Identification
ColorColorless to white, gray, black, flesh-red, burgundy-red, pink, brown, dark brown, mahogany-brown, honey-yellow, yellow, apple-green, blue, pastel green, light blue, azure-blue
Crystal habitFibrous, botryoidal to massive
Cleavage{0001}, {1120} – imperfect
FractureIrregular to conchoidal
Mohs scale hardness5.5
LusterVitreous to resinous
DiaphaneityTransparent to opaque
Specific gravity3.9  4.2
Optical propertiesUniaxial (+)
Refractive indexnω = 1.691  1.694 nε = 1.719  1.725
Birefringenceδ = 0.028
Other characteristicsStrongly fluorescent; may be phosphorescent
References
Major varieties
troostitezinc is partly replaced by manganese

It was discovered in 1829 in the Belgian Vieille-Montagne mine. Armand Lévy was shown samples by a student at the university where he was teaching. Lévy named it after William I of the Netherlands (it is occasionally spelled villemite). The troostite variety is named after Dutch-American mineralogist Gerard Troost.

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