Vermiculite

Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently; commercial furnaces can routinely produce this effect. Vermiculite forms by the weathering or hydrothermal alteration of biotite or phlogopite. Large commercial vermiculite mines exist in the United States, Russia, South Africa, China, and Brazil.

Vermiculite
General
CategoryPhyllosilicates
Formula
(repeating unit)
(Mg,Fe2+,Fe3+)3[(Al,Si)4O10](OH)2·4H2O
IMA symbolVrm
Strunz classification9.EC.50
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/m
Unit cella = 5.24 Å, b = 9.17 Å
c = 28.6 Å; β = 94.6°; Z = 2
Identification
ColorColorless, white, yellow, green, brown, black
Crystal habitAs large crystalline plates to clay-sized particles; lamellar to scaley
CleavagePerfect on {001}
TenacityPliable
Mohs scale hardness1.5–2
LusterGreasy or vitreous (pearly at cleavage planes)
StreakWhite or yellowish, translucent, shiny, light-brown or greenish in color, in some cases. For example, palabora vermuculite.
DiaphaneityTranslucent
Specific gravity2.4–2.7 (0.065–0.130 when exfoliated)
Optical propertiesBiaxial (−)
Refractive indexnα = 1.525 – 1.561 nβ = 1.545 – 1.581 nγ = 1.545 – 1.581
Birefringenceδ = 0.020
PleochroismX in paler shades than Y and Z
References
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