Triphenylphosphine selenide

Triphenylphosphine selenide
Names
	Preferred IUPAC name Triphenyl-λ5-phosphaneselone
	Other names triphenylphosphane selenide
Identifiers
CAS Number	3878-44-2 ;
3D model (JSmol)	Interactive image;
ChemSpider	263833;
ECHA InfoCard	100.021.279
EC Number	223-406-1;
PubChem CID	298720;
UNII	T9S5RC2HL6 ;
CompTox Dashboard (EPA)	DTXSID00959584 ;
	InChI InChI=1S/C18H15PSe/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H Key: ZFVJLNKVUKIPPI-UHFFFAOYSA-N;
	SMILES c1ccc(cc1)P(=[Se])(c2ccccc2)c3ccccc3;
Properties
Chemical formula	C18H15PSe
Molar mass	341.25
Appearance	white solid
Melting point	186.5 to 187.5
Solubility in water	insoluble
Solubility	very soluble in dichloromethane, pyridine, and THF; moderately soluble on heating in acetonitrile, ethanol, and methanol; insoluble in ether
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Triphenylphosphine selenide is an organophosphorus compound with the formula (C₆H₅)₃PSe. It is a white solid which is soluble in most organic solvents. The compound is used in the preparation of other selenium compounds and is itself prepared by the reaction of triphenylphosphine with potassium selenocyanate. Single crystals have been isolated with both monoclinic and triclinic structures (space groups: P2₁/c and P1 respectively); in both cases the geometry at phosphorus is tetrahedral.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.