Triphenylmethane

Triphenylmethane or triphenyl methane (sometimes also known as Tritan), is the hydrocarbon with the formula (C6H5)3CH. This colorless solid is soluble in nonpolar organic solvents and not in water. Triphenylmethane is the basic skeleton of many synthetic dyes called triarylmethane dyes, many of them are pH indicators, and some display fluorescence. A trityl group in organic chemistry is a triphenylmethyl group Ph3C, e.g. triphenylmethyl chloride (trityl chloride) and the triphenylmethyl radical (trityl radical).

Triphenylmethane
Names
Preferred IUPAC name
1,1′,1′′-Methanetriyltribenzene
Other names
Triphenylmethane
1,1′,1′′-Methylidynetrisbenzene
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.007.524
EC Number
  • 208-275-0
UNII
  • InChI=1S/C19H16/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H Y
    Key: AAAQKTZKLRYKHR-UHFFFAOYSA-N Y
  • InChI=1/C19H16/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
    Key: AAAQKTZKLRYKHR-UHFFFAOYAF
  • c1c(cccc1)C(c2ccccc2)c3ccccc3
Properties
C19H16
Molar mass 244.337 g·mol−1
Appearance Colorless solid
Density 1.014 g/cm3
Melting point 92 to 94 °C (198 to 201 °F; 365 to 367 K)
Boiling point 359 °C (678 °F; 632 K)
Insoluble
Solubility Soluble in dioxane and hexane
Acidity (pKa) 33.3
−165.6×10−6 cm3/mol
Hazards
GHS labelling:
Warning
H315, H319, H335
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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