Trimethyl phosphite
Trimethyl phosphite is an organophosphorus compound with the formula P(OCH3)3, often abbreviated P(OMe)3. It is a colorless liquid with a highly pungent odor. It is the simplest phosphite ester and finds used as a ligand in organometallic chemistry and as a reagent in organic synthesis. The molecule features a pyramidal phosphorus(III) center bound to three methoxy groups.
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Names | |||
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Preferred IUPAC name
Trimethyl phosphite | |||
Other names
Trimethoxyphosphine Trimethoxyphosphane | |||
Identifiers | |||
3D model (JSmol) |
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ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.004.065 | ||
PubChem CID |
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UNII | |||
CompTox Dashboard (EPA) |
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Properties | |||
C3H9O3P | |||
Molar mass | 124.08 | ||
Appearance | colorless liquid | ||
Odor | distinctive, pungent | ||
Density | 1.052 | ||
Melting point | −78 °C (−108 °F; 195 K) | ||
Boiling point | 111 °C (232 °F; 384 K) | ||
reacts | |||
Vapor pressure | 24 mmHg (25°C) | ||
Hazards | |||
Flash point | 28 °C; 82 °F; 301 K | ||
NIOSH (US health exposure limits): | |||
PEL (Permissible) |
none | ||
REL (Recommended) |
TWA 2 ppm (10 mg/m3) | ||
IDLH (Immediate danger) |
N.D. | ||
Related compounds | |||
Related compounds |
Dimethyl methylphosphonate | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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