Triflic acid
Triflic acid, the short name for trifluoromethanesulfonic acid, TFMS, TFSA, HOTf or TfOH, is a sulfonic acid with the chemical formula CF3SO3H. It is one of the strongest known acids. Triflic acid is mainly used in research as a catalyst for esterification. It is a hygroscopic, colorless, slightly viscous liquid and is soluble in polar solvents.
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Names | |||
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IUPAC name
Trifluoromethanesulfonic acid | |||
Other names
Triflic acid | |||
Identifiers | |||
3D model (JSmol) |
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ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.014.625 | ||
PubChem CID |
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UNII | |||
CompTox Dashboard (EPA) |
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Properties | |||
CF3SO3H | |||
Molar mass | 150.07121 g/mol | ||
Appearance | Colorless liquid | ||
Density | 1.696 g/mL | ||
Melting point | −40 °C (−40 °F; 233 K) | ||
Boiling point | 162 °C (324 °F; 435 K) | ||
1600 g/L | |||
Vapor pressure | 3.2 | ||
Acidity (pKa) | −14.7±2.0 | ||
Conjugate base | Triflate anion | ||
Viscosity | 1.864–1.881 mm2/s at 20 °C | ||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards |
Causes severe acid burns | ||
GHS labelling: | |||
Danger | |||
H290, H302, H314, H335, H402 | |||
P234, P261, P264, P270, P271, P273, P280, P301+P312+P330, P301+P330+P331, P303+P361+P353, P304+P340+P310, P305+P351+P338+P310, P363, P390, P403+P233, P405, P501 | |||
NFPA 704 (fire diamond) | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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