Torbernite
Torbernite, also known as chalcolite, is a relatively common mineral with the chemical formula Cu[(UO2)(PO4)]2(H2O)12. It is a radioactive, hydrated green copper uranyl phosphate, found in granites and other uranium-bearing deposits as a secondary mineral. The chemical formula of torbernite is similar to that of autunite in which a Cu2+ cation replaces a Ca2+ cation. Torbernite tends to dehydrate to metatorbernite with the sum formula Cu[(UO2)(PO4)]2(H2O)8.
Torbernite | |
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Torbernite crystals from Mashamba West Mine, Kolwezi, Katanga Province, Democratic Republic of the Congo | |
General | |
Category | Phosphate minerals |
Formula (repeating unit) | Cu[(UO2)(PO4)]2(H2O)12 |
IMA symbol | Tor |
Strunz classification | 8.EB.05 |
Crystal system | Tetragonal |
Crystal class | Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m) |
Space group | I4/mmm |
Identification | |
Formula mass | 641 – 713 g/mol, depending the degree of water loss |
Color | Emerald green to apple green |
Crystal habit | Tabular crystals; Foliated to earthy masses and encrustations |
Twinning | Rare on [110] |
Cleavage | [001] Perfect; [100] Distinct |
Fracture | Brittle |
Mohs scale hardness | 2–2.5 |
Luster | Vitreous; pearly |
Streak | Pale green |
Diaphaneity | Transparent to subtranslucent |
Density | measured: 3.22; calculated: 3.264(1) |
Optical properties | Uniaxial (−) |
Refractive index | nω = 1.590 – 1.592 nε = 1.581 – 1.582 |
Birefringence | δ = 0.009 – 0.010 |
Pleochroism | Visible |
Melting point | Decomposes before |
Fusibility | Decomposes before |
Other characteristics | Radioactive |
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