Titanium tetrabromide

Titanium tetrabromide
Names
	IUPAC name Titanium(IV) bromide
	Other names Titanium tetrabromide
Identifiers
CAS Number	7789-68-6 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.029.259
EC Number	232-185-0;
PubChem CID	123263;
UNII	1CBW950X1W ;
CompTox Dashboard (EPA)	DTXSID90894990 ;
	InChI InChI=1S/4BrH.Ti/h4*1H;/q;;;;+4/p-4 Key: UBZYKBZMAMTNKW-UHFFFAOYSA-J;
	SMILES [Ti](Br)(Br)(Br)Br;
Properties
Chemical formula	TiBr4
Molar mass	367.483 g/mol
Appearance	brown crystals ; hygroscopic
Density	3.25 g/cm3
Melting point	39 °C (102 °F; 312 K)
Boiling point	230 °C (446 °F; 503 K)
Solubility in water	hydrolyses
Solubility in other solvents	chlorocarbons, benzene
Structure
Crystal structure	cubic, Pa3, Z = 8
Coordination geometry	Tetrahedral
Dipole moment	0 D
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	corrosive
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H314
Precautionary statements	P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P363, P405
NFPA 704 (fire diamond)	3 0 1
Flash point	Non-flammable
Related compounds
Other anions	Titanium(IV) chloride ; Titanium(IV) fluoride ; Titanium(IV) iodide
Related compounds	Titanium(III) bromide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Titanium tetrabromide is the chemical compound with the formula TiBr₄. It is the most volatile transition metal bromide. The properties of TiBr₄ are an average of TiCl₄ and TiI₄. Some key properties of these four-coordinated Ti(IV) species are their high Lewis acidity and their high solubility in nonpolar organic solvents. TiBr₄ is diamagnetic, reflecting the d⁰ configuration of the metal centre.

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