Tilleyite

Tilleyite is a rarely occurring calcium sorosilicate mineral with formula Ca3[Si2O7]·2CaCO3 (sometimes represented as Ca5(CaCO3)2[Si2O7]). It is chemically a calcium silicate with additional carbonate ions. Tilleyite crystallizes in the monoclinic crystal system and forms only poorly developed, irregularly defined, tabular crystals and spherical grains. In its pure form it is colorless and transparent, however due to multiple refractions of light from lattice defects or polycrystalline formation, it can also appear white, with the transparency decreasing accordingly.

Tilleyite
Tilleyite collected from Crestmore quarries, Riverside County, California
General
CategorySorosilicate
Formula
(repeating unit)
Ca3[Si2O7]·2CaCO3
IMA symbolTly
Strunz classification9.BE.82
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/b
Unit cella = 15.108(3) Å
b = 10.241(1) Å
c = 7.579(1) Å
β = 105.17(1)°
Z = 4
Identification
ColourColourless, white
TwinningSimple twinning {100}, often lamellar; α:twin plane ~ 24°
Cleavage{201} perfect; {100} and {010} poor
LusterVitreous, Dull
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.838 - 2.88
Optical propertiesMonoclinic (+)
Refractive indexnα = 1.605 - 1.617
nβ = 1.626 - 1.635
nγ = 1.651 - 1.654
Birefringenceδ = 0.035 - 0.046
2V angle85-89°
Dispersionr < v
References
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