Thiosulfate

Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S2O2−3. Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, e.g. sodium thiosulfate Na2S2O3. Thiosulfate also refers to the esters of thiosulfuric acid. The prefix thio- indicates that the thiosulfate is a sulfate with one oxygen replaced by sulfur. Thiosulfate is tetrahedral at the central S atom. Thiosulfate salts occur naturally. Thiosulfate ion has C3v symmetry, and is produced by certain biochemical processes. It rapidly dechlorinates water and is notable for its use to halt bleaching in the paper-making industry. Thiosulfate salts are mainly used in dying in textiles and the bleaching of natural substances.

Thiosulfate
Names
IUPAC names
  • Sulfurothioate
  • Trioxidosulfidosulfate(2−)
  • Trioxido-1κ3O-disulfate(SS)(2−)
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
UNII
  • InChI=1S/H2O3S2/c1-5(2,3)4/h(H2,1,2,3,4)/p-2
    Key: DHCDFWKWKRSZHF-UHFFFAOYSA-L
  • [O-]S(=O)(=S)[O-]
Properties
S2O2−3
Molar mass 112.12 g·mol−1
Conjugate acid Thiosulfuric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sodium thiosulfate, commonly called hypo (from "hyposulfite"), was widely used in photography to fix black and white negatives and prints after the developing stage; modern "rapid" fixers use ammonium thiosulfate as a fixing salt because it acts three to four times faster. Some bacteria can metabolise thiosulfates.

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