Tetrathiafulvalene

Tetrathiafulvalene (TTF) is an organosulfur compound with the formula (C3H2S2)2. Studies on this heterocyclic compound contributed to the development of molecular electronics. TTF is related to the hydrocarbon fulvalene, (C5H4)2, by replacement of four CH groups with sulfur atoms. Over 10,000 scientific publications discuss TTF and its derivatives.

Tetrathiafulvalene
Names
Preferred IUPAC name
2,2′-Bi(1,3-dithiolylidene)
Other names
Δ2,2-Bi-1,3-dithiole
Identifiers
3D model (JSmol)
1282106
ChEBI
ChemSpider
ECHA InfoCard 100.045.979
EC Number
  • 250-593-7
UNII
  • InChI=1S/C6H4S4/c1-2-8-5(7-1)6-9-3-4-10-6/h1-4H Y
    Key: FHCPAXDKURNIOZ-UHFFFAOYSA-N Y
  • InChI=1/C6H4S4/c1-2-8-5(7-1)6-9-3-4-10-6/h1-4H
    Key: FHCPAXDKURNIOZ-UHFFFAOYAZ
  • S1C=CSC1=C2SC=CS2
Properties
C6H4S4
Molar mass 204.34 g·mol−1
Appearance Yellow solid
Melting point 116 to 119 °C (241 to 246 °F; 389 to 392 K)
Boiling point Decomposes
Insoluble
Solubility in organic solvents Soluble
Structure
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
combustible
GHS labelling:
Warning
H317
P261, P280, P302+P352, P333+P313, P363, P501
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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