TPPTS

3,3′,3′′-Phosphanetriyltris(benzenesulfonic acid) trisodium salt (abbreviated TPPTS), is an organic compound that is also known as sodium triphenylphosphine trisulfonate. The compound has the formula P(C6H4SO3Na)3. This white solid is an unusual example of a water-soluble phosphine. Its complexes are also water-soluble. Its complex with rhodium is used in the industrial production of butyraldehyde.

TPPTS
Names
Preferred IUPAC name
Trisodium 3,3′,3′′-phosphanetriyltri(benzene-1-sulfonate)
Other names
  • Trisodium 3-bis(3-sulfonatophenyl)phosphanylbenzenesulfonate
  • 3,3′,3′′-Phosphanetriyltris(benzenesulfonic acid) trisodium salt
  • Tris(3-sulfophenyl)phosphine trisodium salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.058.706
EC Number
  • 264-596-6
  • InChI=1S/C18H15O9PS3.3Na/c19-29(20,21)16-7-1-4-13(10-16)28(14-5-2-8-17(11-14)30(22,23)24)15-6-3-9-18(12-15)31(25,26)27;;;/h1-12H,(H,19,20,21)(H,22,23,24)(H,25,26,27);;;/q;3*+1/p-3 N
    Key: MYAJTCUQMQREFZ-UHFFFAOYSA-K N
  • c1cc(cc(c1)S(=O)(=O)[O-])P(c2cccc(c2)S(=O)(=O)[O-])c3cccc(c3)S(=O)(=O)[O-].[Na+].[Na+].[Na+]
Properties
C18H12Na3O9PS3
Molar mass 568.41 g·mol−1
Appearance White microcrystalline solid
Soluble
Hazards
GHS labelling:
Warning
H315, H319, H335
P280, P302+P352, P304+P340, P305+P351+P338, P312, P332+P313, P337+P313
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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