Sodium sulfate

Sodium sulfate (also known as sodium sulphate or sulfate of soda) is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are white solids that are highly soluble in water. With an annual production of 6 million tonnes, the decahydrate is a major commodity chemical product. It is mainly used as a filler in the manufacture of powdered home laundry detergents and in the Kraft process of paper pulping for making highly alkaline sulfides.

Sodium sulfate
Names
IUPAC name
Sodium sulfate
Other names
Sodium sulphate
Disodium sulfate
Sulfate of sodium
Thenardite (anhydrous mineral)
Glauber's salt (decahydrate)
Sal mirabilis (decahydrate)
Mirabilite (decahydrate mineral)
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.928
E number E514(i) (acidity regulators, ...)
RTECS number
  • WE1650000
UNII
  • InChI=1S/2Na.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2 Y
    Key: PMZURENOXWZQFD-UHFFFAOYSA-L Y
  • InChI=1S/2Na.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2
  • InChI=1S/2Na.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2
    Key: PMZURENOXWZQFD-UHFFFAOYSA-L
  • [Na+].[Na+].[O-]S([O-])(=O)=O
Properties
Na2SO4
Molar mass 142.04 g/mol (anhydrous)
322.20 g/mol (decahydrate)
Appearance white crystalline solid
hygroscopic
Odor odorless
Density 2.664 g/cm3 (anhydrous)
1.464 g/cm3 (decahydrate)
Melting point 884 °C (1,623 °F; 1,157 K) (anhydrous)
32.38 °C (decahydrate)
Boiling point 1,429 °C (2,604 °F; 1,702 K) (anhydrous)
anhydrous:
4.76 g/100 mL (0 °C)
28.1 g/100 mL (25 °C)
42.7 g/100 mL (100 °C)
heptahydrate:
19.5 g/100 mL (0 °C)
44 g/100 mL (20 °C)
Solubility insoluble in ethanol
soluble in glycerol, water, and hydrogen iodide
52.0·10−6 cm3/mol
1.468 (anhydrous)
1.394 (decahydrate)
Structure
orthorhombic (anhydrous)
monoclinic (decahydrate)
Pharmacology
A06AD13 (WHO) A12CA02 (WHO)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant
NFPA 704 (fire diamond)
1
0
0
Flash point Non-flammable
Safety data sheet (SDS) ICSC 0952
Related compounds
Other anions
Sodium selenate
Sodium tellurate
Other cations
Lithium sulfate
Potassium sulfate
Rubidium sulfate
Caesium sulfate
Related compounds
Sodium bisulfate
Sodium sulfite
Sodium persulfate
Sodium pyrosulfate
Supplementary data page
Sodium sulfate (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references
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