Sodium pertechnetate

Sodium pertechnetate is the inorganic compound with the formula NaTcO4. This colourless salt contains the pertechnetate anion, TcO
4
that has slightly distorted tetrahedron symmetry both at 296 K and at 100 K while the coordination polyhedron of the sodium cation is different from typical for scheelite structure. The radioactive 99m
Tc
O
4
anion is an important radiopharmaceutical for diagnostic use. The advantages to 99m
Tc
include its short half-life of 6 hours and the low radiation exposure to the patient, which allow a patient to be injected with activities of more than 30 millicuries. Na[99m
Tc
O
4
]
is a precursor to a variety of derivatives that are used to image different parts of the body.

Sodium pertechnetate
Names
IUPAC name
Sodium technetate(VII)
Other names
sodium tetraoxotechnetate (VII)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.870
EC Number
  • 237-273-2
UNII
  • InChI=1S/Na.4O.Tc/q+1;;;;-1;
    Key: MKADDTFVKFMZGF-UHFFFAOYSA-N
  • [Na+].[O-][Tc](=O)(=O)=O
  • 99
    Tc
    : [O-][99Tc](=O)(=O)=O.[Na+]
Properties
NaTcO4
Molar mass 169.89 g/mol
Appearance White or pale pink solid
Melting point < 1,063 K (790 °C; 1,454 °F)
Soluble
Structure
Scheelite
I41/a
a = 5.3325(1) Å, c = 11.8503(3) Å
4
Related compounds
Other anions
Sodium permanganate; sodium perrhenate
Other cations
Ammonium pertechnetate
Related compounds
Technetium heptoxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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