Sodium bisulfite

Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO3. Sodium bisulfite in fact is not a real compound, but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions. It appears in form of white or yellowish-white crystals with an odor of sulfur dioxide. Regardless of its ill-defined nature, sodium bisulfite is used in many different industries such as a food additive with E number E222 in the food industry, a reducing agent in the cosmetic industry, and a decomposer of residual hypochlorite used in the bleaching industry.

Sodium bisulfite
Names
IUPAC name
Sodium hydrogen sulfite
Other names
E222, sodium bisulphite
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.028.680
E number E222 (preservatives)
RTECS number
  • VZ2000000
UNII
  • InChI=1S/Na.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-1 Y
    Key: DWAQJAXMDSEUJJ-UHFFFAOYSA-M Y
  • InChI=1/Na.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-1
    Key: DWAQJAXMDSEUJJ-REWHXWOFAL
  • [Na+].[O-]S(=O)O
Properties
NaHSO3
Molar mass 104.061 g/mol
Appearance White solid
Odor Slight sulfurous odor
Density 1.48 g/cm3
Melting point 150 °C (302 °F; 423 K)
Boiling point 315 °C (599 °F; 588 K)
42 g/100mL
1.526
Hazards
GHS labelling:
H302
P301+P312+P330
NFPA 704 (fire diamond)
2
0
1
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
none
REL (Recommended)
TWA 5 mg/m3
IDLH (Immediate danger)
N.D.
Related compounds
Other anions
Sodium sulfite
Sodium metabisulfite
Sodium biselenite
Other cations
Potassium bisulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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