Sodium aluminate

Sodium aluminate is an inorganic chemical that is used as an effective source of aluminium hydroxide for many industrial and technical applications. Pure sodium aluminate (anhydrous) is a white crystalline solid having a formula variously given as NaAlO2, NaAl(OH)4 (hydrated), Na2O·Al2O3, or Na2Al2O4. Commercial sodium aluminate is available as a solution or a solid.
Other related compounds, sometimes called sodium aluminate, prepared by reaction of Na2O and Al2O3 are Na5AlO4 which contains discrete AlO45− anions, Na7Al3O8 and Na17Al5O16 which contain complex polymeric anions, and NaAl11O17, once mistakenly believed to be β-alumina, a phase of aluminium oxide.

Sodium aluminate

Crystal structure with sodium in yellow, aluminium in grey, and oxygen in red

Sodium metaaluminate sample
Names
IUPAC name
Sodium aluminate
Other names
Sodium aluminium oxide,
Sodium metaaluminate
Aluminate, ((AlO2)1−), sodium
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.728
EC Number
  • 215-100-1
UNII
  • InChI=1S/Al.Na.2O/q-1;+1;;
    Key: IYJYQHRNMMNLRH-UHFFFAOYSA-N
  • O=[Al-]=O.[Na+]
Properties
NaAlO2
Molar mass 81.97 g/mol
Appearance white powder (sometimes light-yellowish)
hygroscopic/ when dissolved in water a colloidal black solution is formed
Odor odorless
Density 1.5 g/cm3
Melting point 1,650 °C (3,000 °F; 1,920 K)
highly soluble
Solubility Insoluble in alcohol
1.566
Structure
orthorhombic
Thermochemistry
73.6 J/mol K
70.4 J/mol K
-1133.2 kJ/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.