Smoky quartz

Smoky quartz is a brownish grey, translucent variety of quartz that ranges in clarity from almost complete transparency to an almost-opaque brownish-gray or black crystals. The color of smoky quartz is produced when natural radiation, emitted from the surrounding rock, activates color centers around aluminum impurities within the crystalline quartz.

Smoky quartz
General
CategorySilicate minerals
Formula
(repeating unit)
SiO2
Strunz classification04.DA.05
Dana classification75.01.03.01
Crystal systemα-quartz: trigonal trapezohedral class 3 2; β-quartz: hexagonal 622
Space groupTrigonal 32
Unit cella = 4.9133 Å, c = 5.4053 Å; Z=3
Identification
ColourBrown to grey, opaque
Crystal habit6-sided prism ending in 6-sided pyramid (typical), drusy, fine-grained to microcrystalline, massive
TwinningCommon Dauphine law, Brazil law and Japan law
Cleavage{0110} Indistinct
FractureConchoidal
TenacityBrittle
Mohs scale hardness7 – lower in impure varieties (defining mineral)
LustreVitreous – waxy to dull when massive
StreakWhite
DiaphaneityTransparent to nearly opaque
Specific gravity2.65; variable 2.59–2.63 in impure varieties
Optical propertiesUniaxial (+)
Refractive indexnω = 1.543–1.545
nε = 1.552–1.554
Birefringence+0.009 (B-G interval)
Pleochroismweak, from red-brown to green-brown
Melting point1670 °C (β tridymite) 1713 °C (β cristobalite)
SolubilityInsoluble at STP; 1 ppmmass at 400 °C and 500 lb/in2 to 2600 ppmmass at 500 °C and 1500 lb/in2
Other characteristicslattice: hexagonal, Piezoelectric, may be triboluminescent, chiral (hence optically active if not racemic)
References


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