Silver subfluoride

Silver subfluoride is the inorganic compound with the formula Ag2F. This is an unusual example of a compound where the oxidation state of silver is fractional. The compound is produced by the reaction of silver and silver(I) fluoride:

Ag + AgF → Ag2F
Silver subfluoride
Names
IUPAC name
silver(0,I) fluoride
Identifiers
3D model (JSmol)
  • InChI=1S/2Ag.FH/h;;1H/q;+1;/p-1
    Key: NYHLXUAEPHSVOU-UHFFFAOYSA-M
  • F[Ag].[Ag]
Properties
Ag2F
Molar mass 234.734 g/mol
Appearance Bronze-colored crystals with green luster
Density 8.6 g/cm3, solid
Melting point 90 °C (194 °F; 363 K) decomposition
reacts
Related compounds
Related compounds
Silver(I) fluoride
Silver(II) fluoride
Silver(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

It forms small crystals with a bronze reflex and is a good conductor of electricity. On contact with water almost instant hydrolysis occurs with the precipitation of silver (Ag) powder.

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