Silicon tetraiodide

Silicon tetraiodide is the chemical compound with the formula SiI4. It is a tetrahedral molecule with Si-I bond lengths of 2.432(5) Å.

Silicon tetraiodide
Names
Other names
silicon tetraiodide
Tetraiodosilane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.355
EC Number
  • 236-706-2
  • InChI=1S/I4Si/c1-5(2,3)4 Y
    Key: CFTHARXEQHJSEH-UHFFFAOYSA-N Y
  • InChI=1/I4Si/c1-5(2,3)4
    Key: CFTHARXEQHJSEH-UHFFFAOYAL
  • I[Si](I)(I)I
Properties
SiI4
Molar mass 535.7034 g/mol
Appearance white powder
Density 4.198 g/cm3
Melting point 120.5 °C (248.9 °F; 393.6 K)
Boiling point 287.4 °C (549.3 °F; 560.5 K)
reacts
Solubility in organic solvents soluble
Structure
tetrahedral
Hazards
GHS labelling:
Danger
H301, H311, H314, H317, H334, H360
P201, P202, P260, P261, P264, P270, P272, P280, P281, P285, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P308+P313, P310, P312, P321, P322, P330, P333+P313, P342+P311, P361, P363, P405, P501
NFPA 704 (fire diamond)
2
0
0
Related compounds
Other anions
Silicon tetrafluoride
Silicon tetrachloride
Silicon tetrabromide
Other cations
Carbon tetraiodide
Germanium tetraiodide
Tin(IV) iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

SiI4 is a precursor to silicon amides of the formula Si(NR2)4 (R = alkyl). It has also been of interest in the manufacture and etching of silicon in microelectronics.

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