Selenium tetrachloride

Selenium tetrachloride is the inorganic compound composed with the formula SeCl4. This compound exists as yellow to white volatile solid. It is one of two commonly available selenium chlorides, the other example being selenium monochloride, Se2Cl2. SeCl4 is used in the synthesis of other selenium compounds.

Selenium tetrachloride
Names
IUPAC name
Selenium tetrachloride
Other names
Selenium(IV) chloride, tetrachloro-λ4-selane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.036
EC Number
  • 233-053-5
RTECS number
  • VS7875000
UNII
  • InChI=1S/Cl4Se/c1-5(2,3)4 Y
    Key: LNBXMNQCXXEHFT-UHFFFAOYSA-N Y
  • InChI=1/Cl4Se/c1-5(2,3)4
    Key: LNBXMNQCXXEHFT-UHFFFAOYAD
  • Cl[Se](Cl)(Cl)Cl
Properties
SeCl4
Molar mass 220.771 g/mol
Appearance white to yellow crystals
Density 2.6 g/cm3, solid
Melting point sublimes at 191.4 °C
decomposes in water
Structure
Monoclinic, mS80
C12/c1, No. 15
Seesaw (gas phase)
Hazards
GHS labelling:
Danger
H301, H331, H373, H410
P260, P261, P264, P270, P271, P273, P301+P310, P304+P340, P311, P314, P321, P330, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
3
0
2
Flash point non-flammable
Related compounds
Other anions
Selenium tetrafluoride
Selenium tetrabromide
Selenium dioxide
Other cations
Dichlorine monoxide
Sulfur tetrachloride
Tellurium tetrachloride
Related compounds
Selenium dichloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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