Scandium nitride

Scandium nitride (ScN) is a binary III-V indirect bandgap semiconductor. It is composed of the scandium cation and the nitride anion. It forms crystals that can be grown on tungsten foil through sublimation and recondensation. It has a rock-salt crystal structure with lattice constant of 0.451 nanometer, an indirect bandgap of 0.9 eV and direct bandgap of 2 to 2.4 eV. These crystals can be synthesized by dissolving nitrogen gas with indium-scandium melts, magnetron sputtering, MBE, HVPE and other deposition methods. Scandium nitride is also an effective gate for semiconductors on a silicon dioxide (SiO2) or hafnium dioxide (HfO2) substrate.

Scandium nitride
Names
IUPAC name
Scandium nitride
Other names
Azanylidynescandium
Nitridoscandium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.042.938
EC Number
  • 247-247-2
  • InChI=1S/N.Sc
    Key: CUOITRGULIVMPC-UHFFFAOYSA-N
  • N#[Sc]
Properties
ScN
Molar mass 58.963
Density 4.4 g/cm3
Melting point 2,600 °C (4,710 °F; 2,870 K)
Hazards
GHS labelling:
Danger
H228
Related compounds
Other anions
Scandium phosphide
Scandium arsenide
Scandium antimonide
Scandium bismuthide
Other cations
Yttrium nitride
Lutetium nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references


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