Ruthenium tetroxide

Ruthenium tetroxide is the inorganic compound with the formula RuO4. It is a yellow volatile solid that melts near room temperature. It has the odor of ozone. Samples are typically black due to impurities. The analogous OsO4 is more widely used and better known. It is also the anhydride of hyperruthenic acid (H2RuO5). One of the few solvents in which RuO4 forms stable solutions is CCl4.

Ruthenium(VIII) oxide
Names
IUPAC name
Ruthenium(VIII) oxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.039.815
EC Number
  • 243-813-8
UNII
  • InChI=1S/4O.Ru
    Key: GJFMDWMEOCWXGJ-UHFFFAOYSA-N
  • O=[Ru](=O)(=O)=O
Properties
RuO4
Molar mass 165.07 g/mol
Appearance yellow easily melting solid
Odor pungent
Density 3.29 g/cm3
Melting point 25.4 °C (77.7 °F; 298.5 K)
Boiling point 40.0 °C (104.0 °F; 313.1 K)
2% w/v at 20 °C
Solubility in other solvents Soluble in
Carbon tetrachloride
Chloroform
Structure
tetrahedral
zero
Hazards
NFPA 704 (fire diamond)
3
0
1
Safety data sheet (SDS) external MSDS sheet
Related compounds
Related compounds
Ruthenium dioxide
Ruthenium trichloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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