Trirhenium nonachloride
Trirhenium nonachloride is a compound with the formula ReCl3, sometimes also written Re3Cl9. It is a dark red hygroscopic solid that is insoluble in ordinary solvents. The compound is important in the history of inorganic chemistry as an early example of a cluster compound with metal-metal bonds. It is used as a starting material for synthesis of other rhenium complexes.
Names | |
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IUPAC name
Rhenium(III) chloride | |
Other names
Rhenium trichloride | |
Identifiers | |
3D model (JSmol) |
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ECHA InfoCard | 100.033.610 |
EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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Properties | |
ReCl3 | |
Molar mass | 292.57 g/mol |
Appearance | red, crystalline, nonvolatile solid |
Density | 4800 kg/m3 |
Melting point | N/A |
Boiling point | 500 °C (932 °F; 773 K) (decomposes) |
hydrolyzes to form Re2O3.xH2O. | |
Structure | |
Rhombohedral, hR72 | |
R-3m, No. 166 | |
(trimeric solid and in solution) (dimeric in acetic acid) | |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards |
Corrosive (C) |
Safety data sheet (SDS) | External MSDS |
Related compounds | |
Other anions |
Rhenium tribromide Rhenium triiodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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