Trirhenium nonachloride

Trirhenium nonachloride is a compound with the formula ReCl3, sometimes also written Re3Cl9. It is a dark red hygroscopic solid that is insoluble in ordinary solvents. The compound is important in the history of inorganic chemistry as an early example of a cluster compound with metal-metal bonds. It is used as a starting material for synthesis of other rhenium complexes.

Trirhenium nonachloride
Names
IUPAC name
Rhenium(III) chloride
Other names
Rhenium trichloride
Identifiers
3D model (JSmol)
ECHA InfoCard 100.033.610
EC Number
  • 236-987-1
  • InChI=1S/3ClH.Re/h3*1H;/q;;;+3/p-3
  • Cl[Re](Cl)Cl
Properties
ReCl3
Molar mass 292.57 g/mol
Appearance red, crystalline, nonvolatile solid
Density 4800 kg/m3
Melting point N/A
Boiling point 500 °C (932 °F; 773 K) (decomposes)
hydrolyzes to form Re2O3.xH2O.
Structure
Rhombohedral, hR72
R-3m, No. 166
(trimeric solid and in solution)
(dimeric in acetic acid)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive (C)
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Rhenium tribromide
Rhenium triiodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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