Pyrophyllite

Pyrophyllite is a phyllosilicate mineral composed of aluminium silicate hydroxide: Al2Si4O10(OH)2. It occurs in two forms (habits): crystalline folia and compact masses; distinct crystals are not known.

Pyrophyllite
Pearly radial cluster of pyrophyllite from Hillsborough District, Orange County, North Carolina (Size: 11 × 7.3 × 6.6 cm)
General
CategorySilicate minerals
Formula
(repeating unit)
Al2Si4O10(OH)2
IMA symbolPrl
Crystal systemMonoclinic or triclinic
Crystal classPrismatic (2/m)
or pinacoidal (1)
Space groupC2/c or C1
Unit cella = 5.16 Å,
b = 8.966(3) Å,
c = 9.347(6) Å; α = 91.18°,
β = 100.46°, γ = 89.64°; Z = 2
Identification
Formula mass360.31 g/mol
ColorBrown green, brownish yellow, greenish, gray green, gray white
Crystal habitCompact spherulitic aggregates of needlelike radiating crystals; as fine grained foliated laminae, granular, massive
Cleavage[001] Perfect
TenacityFlexible inelastic
Mohs scale hardness1.5–2
LusterPearly to dull
Streakwhite
DiaphaneityTranslucent to opaque
Specific gravity2.65 – 2.9
Optical propertiesBiaxial (−)
Refractive indexnα=1.534–1.556, nβ=1.586–1.589, nγ=1.596–1.601
Birefringenceδ =0.0450–0.0620
2V angle53–62
FusibilityInfusible, exfoliates
References

The folia have a pronounced pearly luster, owing to the presence of a perfect cleavage parallel to their surfaces: they are flexible but not elastic, and are usually arranged radially in fan-like or spherical groups. This variety, when heated, exfoliates and swells up to many times its original volume. The color of both varieties is white, pale green, greyish or yellowish; they are very soft (hardness of 1.0 to 1.5) and are greasy to the touch. The specific gravity is 2.65–2.85. The two varieties are thus very similar to talc.

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