Potassium tetraperoxochromate(V)

Potassium peroxochromate, potassium tetraperoxochromate(V), or simply potassium perchromate, is an inorganic compound having the chemical formula K3[Cr(O2)4]. It is a red-brown paramagnetic solid. It is the potassium salt of tetraperoxochromate(V), one of the few examples of chromium in the +5 oxidation state and one of the rare examples of a complex stabilized only by peroxide ligands. This compound is used as a source of singlet oxygen.

Potassium tetraperoxochromate(V)
Names
IUPAC name
Potassium tetraperoxochromate(V)
Other names
  • Potassium perchromate
  • Potassium peroxochromate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Cr.3K.4O2/c;;;;4*1-2/q+5;3*+1;4*-2
    Key: JSURYJVAXIVWCV-UHFFFAOYSA-N
  • [O-][O-].[O-][O-].[O-][O-].[O-][O-].[K+].[K+].[K+].[Cr+5]
Properties
K3[Cr(O2)4]
Molar mass 297.286 g/mol
Appearance red brown
Melting point 70 °C (158 °F; 343 K) (decomposes)
Poorly soluble (0 °C)
Reacts (45 °C)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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