Potassium hydride
Potassium hydride, KH, is the inorganic compound of potassium and hydrogen. It is an alkali metal hydride. It is a white solid, although commercial samples appear gray. It is a powerful superbase that is useful in organic synthesis. It is sold commercially as a slurry (~35%) in mineral oil or sometimes paraffin wax to facilitate dispensing.
Potassium cation, K+ Hydrogen anion, H− | |
Names | |
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IUPAC name
Potassium hydride | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.028.823 |
EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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Properties | |
KH | |
Molar mass | 40.1062 g/mol |
Appearance | white to gray crystalline powder |
Density | 1.43 g/cm3 |
Melting point | decomposes at ~400 °C |
reacts | |
Solubility | insoluble in benzene, diethyl ether, carbon disulfide |
Structure | |
cubic, cF8 | |
Fm3m, No. 225 | |
Thermochemistry | |
Heat capacity (C) |
37.91 J/(mol⋅K) |
Std enthalpy of formation (ΔfH⦵298) |
-57.82 kJ/mol |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards |
corrosive, pyrophoric, reacts violently with acids and water |
NFPA 704 (fire diamond) | |
Related compounds | |
Other cations |
Lithium hydride Sodium hydride Rubidium hydride Caesium hydride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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