Potassium hydride

Potassium hydride, KH, is the inorganic compound of potassium and hydrogen. It is an alkali metal hydride. It is a white solid, although commercial samples appear gray. It is a powerful superbase that is useful in organic synthesis. It is sold commercially as a slurry (~35%) in mineral oil or sometimes paraffin wax to facilitate dispensing.

Potassium hydride

  Potassium cation, K+
  Hydrogen anion, H
Names
IUPAC name
Potassium hydride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.823
EC Number
  • 232-151-5
  • InChI=1S/K.H/q+1;-1 Y
    Key: OCFVSFVLVRNXFJ-UHFFFAOYSA-N Y
  • InChI=1S/K.H/q+1;-1
    Key: OCFVSFVLVRNXFJ-UHFFFAOYAO
  • Key: OCFVSFVLVRNXFJ-UHFFFAOYSA-N
  • [H-].[K+]
Properties
KH
Molar mass 40.1062 g/mol
Appearance white to gray crystalline powder
Density 1.43 g/cm3
Melting point decomposes at ~400 °C
reacts
Solubility insoluble in benzene, diethyl ether, carbon disulfide
Structure
cubic, cF8
Fm3m, No. 225
Thermochemistry
37.91 J/(mol⋅K)
-57.82 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
corrosive, pyrophoric, reacts violently with acids and water
NFPA 704 (fire diamond)
3
3
2
Related compounds
Other cations
Lithium hydride
Sodium hydride
Rubidium hydride
Caesium hydride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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