Potassium ferrocyanide

Potassium ferrocyanide is the inorganic compound with formula K4[Fe(CN)6]·3H2O. It is the potassium salt of the coordination complex [Fe(CN)6]4−. This salt forms lemon-yellow monoclinic crystals.

Potassium ferrocyanide
Names
IUPAC name
Potassium hexacyanidoferrate(II)
Other names
(Yellow) Prussiate of Potash,
Potassium hexacyanoferrate (II) trihydrate,
Tetrapotassium ferrocyanide trihydrate,
Ferrate hexacyano tetrapotassium trihydrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.279
EC Number
  • 237-722-2
E number E536 (acidity regulators, ...)
UNII
  • InChI=1S/6CN.Fe.4K.3H2O/c6*1-2;;;;;;;;/h;;;;;;;;;;;3*1H2/q6*-1;+2;4*+1;;;
    Key: UTYXJYFJPBYDKY-UHFFFAOYSA-N
  • [K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+]
Properties
K4[Fe(CN)6]
Molar mass 368.35 g/mol (anhydrous)
422.388 g/mol (trihydrate)
Appearance Light yellow, crystalline granules
Density 1.85 g/cm3 (trihydrate)
Boiling point (decomposes)
trihydrate
28.9 g/100 mL (20 °C)
Solubility insoluble in ethanol, ether
130.0·10−6 cm3/mol
Hazards
GHS labelling:
Warning
H411
NFPA 704 (fire diamond)
1
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
6400 mg/kg (oral, rat)
Related compounds
Other anions
Potassium ferricyanide
Other cations
Sodium ferrocyanide
Prussian blue
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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