Potassium bifluoride
Potassium bifluoride is the inorganic compound with the formula K[HF2]. This colourless salt consists of the potassium cation (K+) and the bifluoride anion ([HF2]−). The salt is used as an etchant for glass. Sodium bifluoride is related and is also of commercial use as an etchant as well as in cleaning products.
Names | |
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IUPAC name
Potassium bifluoride | |
Other names
Potassium hydrogen difluoride | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.029.233 |
EC Number |
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PubChem CID |
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RTECS number |
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UNII | |
UN number | 1811 |
CompTox Dashboard (EPA) |
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Properties | |
K[HF2] | |
Molar mass | 78.103 g/mol |
Appearance | colourless solid |
Odor | slightly acidic |
Density | 2.37 g/cm3 |
Melting point | 238.7 °C (461.7 °F; 511.8 K) |
Boiling point | decomposes |
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Solubility | soluble in ethanol |
Structure | |
monoclinic | |
Thermochemistry | |
Std molar entropy (S⦵298) |
45.56 J/(mol·K) |
Std enthalpy of formation (ΔfH⦵298) |
-417.26 kJ/(mol·K) |
Hazards | |
GHS labelling: | |
Danger | |
H301, H310, H314 | |
P260, P262, P264, P270, P280, P301+P310, P301+P330+P331, P302+P350, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P322, P330, P361, P363, P405, P501 | |
Flash point | non flammable |
Related compounds | |
Other anions |
Potassium fluoride |
Other cations |
Sodium bifluoride, ammonium bifluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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