Plutonium(IV) oxide

Plutonium(IV) oxide, or plutonia, is a chemical compound with the formula PuO2. This high melting-point solid is a principal compound of plutonium. It can vary in color from yellow to olive green, depending on the particle size, temperature and method of production.

Plutonium(IV) oxide
Names
IUPAC name
Plutonium(IV) oxide
Systematic IUPAC name
Plutonium(4+) oxide
Other names
Plutonium dioxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.840
EC Number
  • 235-037-3
  • InChI=1S/2O.Pu/q2*-2;+4 Y
    Key: FLDALJIYKQCYHH-UHFFFAOYSA-N Y
  • [O-2].[O-2].[Pu+4]
Properties
O2Pu
Molar mass 276 g·mol−1
Appearance Dark yellow crystals
Density 11.5 g cm−3
Melting point 2,744 °C (4,971 °F; 3,017 K)
Boiling point 2,800 °C (5,070 °F; 3,070 K)
Structure
Fluorite (cubic), cF12
Fm3m, No. 225
a = 539.5 pm
Tetrahedral (O2−); cubic (PuIV)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Radioactive
NFPA 704 (fire diamond)
4
0
0
Flash point non-flammable
Related compounds
Other cations
Uranium(IV) oxide
Neptunium(IV) oxide
Americium(IV) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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