Petroleum ether

Petroleum ether is the petroleum fraction consisting of aliphatic hydrocarbons and boiling in the range 35–60 °C, and commonly used as a laboratory solvent. Despite the name, petroleum ether is not an ether; the term is used only figuratively, signifying extreme lightness and volatility.

Petroleum ether
Names
Other names
Benzine; Light ligroin; Light petroleum; pether
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.029.498
EC Number
  • 232-453-7
UNII
Properties
Molar mass 82.2 g/mol
Appearance Volatile, clear, colorless and non-fluorescent liquid
Density 0.653 g/mL
Melting point < −73 °C (−99 °F; 200 K)
Boiling point 42–62 °C (108–144 °F; 315–335 K)
insoluble
Solubility in Ethanol soluble
Vapor pressure 31 kPa (20 °C)
1.370
Viscosity 0.46 mPa·s
Hazards
GHS labelling:
Danger
H225, H304, H315, H336, H411
P210, P243, P273, P301+P310, P301+P330+P331, P303+P361+P353, P403+P235
NFPA 704 (fire diamond)
2
4
0
Flash point < 0 °C (32 °F; 273 K)
246.11 °C (475.00 °F; 519.26 K)
Explosive limits 1.4–5.9 %
300 ppm (1370 mg/m3) 8 h TWA (TWA)
Lethal dose or concentration (LD, LC):
3400 ppm (rat, 4 h)
NIOSH (US health exposure limits):
PEL (Permissible)
100 ppm (400 mg/m3) 8 h TWA
REL (Recommended)
100 ppm (400 mg/m3) 10 h TWA
IDLH (Immediate danger)
1000 ppm
Related compounds
Related compounds
Ligroin, Petroleum benzine, Petroleum spirit, Stoddard solvent, Naphtha, White spirit
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
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