Perbromate

In chemistry, the perbromate ion is the anion having the chemical formula BrO
4
. It is an oxyanion of bromine, the conjugate base of perbromic acid, in which bromine has the oxidation state +7. Unlike its chlorine (ClO4) and iodine (IO4) analogs, it is difficult to synthesize. It has tetrahedral molecular geometry.

Perbromate

Space-filling model of the perbromate anion, BrO
4
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
  • InChI=1S/BrHO4/c2-1(3,4)5/h(H,2,3,4,5)/p-1
    Key: LLYCMZGLHLKPPU-UHFFFAOYSA-M
  • [O-]Br(=O)(=O)=O
Properties
BrO4
Molar mass 143.901 g·mol−1
Related compounds
Related compounds
bromide
hypobromite
bromite
bromate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

The term perbromate also refers to a compound that contains the BrO
4
anion or the –OBrO
3
functional group.

The perbromate ion is a strong oxidizing agent. The reduction potential for the BrO
4
/Br couple is +0.68 V at pH 14. This is comparable to selenite's reduction potential.

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