Palladium(II) chloride
Palladium(II) chloride, also known as palladium dichloride and palladous chloride, are the chemical compounds with the formula PdCl2. PdCl2 is a common starting material in palladium chemistry – palladium-based catalysts are of particular value in organic synthesis. It is prepared by the reaction of chlorine with palladium metal at high temperatures.
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Other names
Palladium dichloride, Palladous chloride | |
Identifiers | |
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ChemSpider | |
ECHA InfoCard | 100.028.724 |
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Properties | |
PdCl2 | |
Molar mass | 177.326 g/mol (anhydrous) 213.357 g/mol (dihydrate) |
Appearance | dark red solid hygroscopic (anhydrous) dark brown crystals (dihydrate) |
Density | 4.0 g/cm3 |
Melting point | 679 °C (1,254 °F; 952 K) (decomposes) |
soluble in trace amounts, better solubility in cold water | |
Solubility | soluble in organic solvents dissolves rapidly in HCl |
−38.0×10−6 cm3/mol | |
Structure | |
rhombohedral | |
square planar | |
Hazards | |
Flash point | Non-flammable |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) |
2704 mg/kg (rat, oral) |
Related compounds | |
Other anions |
Palladium(II) fluoride Palladium(II) bromide Palladium(II) iodide |
Other cations |
Nickel(II) chloride Platinum(II) chloride Platinum(II,IV) chloride Platinum(IV) chloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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