Nitrate radical

Trioxidonitrogen(•) or nitrate radical is an oxide of nitrogen with formula NO
3
, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.

Nitrate radical
Names
IUPAC name
Nitrate radical
Systematic IUPAC name
Trioxidonitrogen(•)
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
1573
  • InChI=1S/NO3/c2-1(3)4
    Key: YPJKMVATUPSWOH-UHFFFAOYSA-N
  • [N+](=O)([O-])[O]
Properties
NO3
Molar mass 62.004 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Like nitrogen dioxide NO
2
, it is a radical (a molecule with an unpaired valence electron), which makes it paramagnetic. It is the uncharged counterpart of the nitrate anion NO
3
and an isomer of the peroxynitrite radical OONO.

Nitrogen trioxide is an important intermediate in reactions between atmospheric components, including the destruction of ozone.

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