Nickeline

Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.

Nickeline
General
CategoryArsenide mineral
Formula
(repeating unit)
nickel arsenide (NiAs)
IMA symbolNc
Strunz classification2.CC.05
Crystal systemHexagonal
Crystal classDihexagonal dipyramidal (6/mmm)
H-M symbol: (6/m 2/m 2/m)
Space groupP63/mmc
Unit cella = 3.602 Å, c = 5.009 Å; Z = 2
Identification
ColorPale copper red with blackish tarnish. white with strong yellowish pink hue on polished section strongly anisotropic
Crystal habitMassive columnar to reniform, rarely as distorted, horizontally striated, {1011} terminated crystals
TwinningOn {1011} producing fourlings
Cleavage{1010} Imperfect, {0001} Imperfect
FractureConchoidal
TenacityBrittle
Mohs scale hardness5 – 5.5
Lustermetallic
Streakbrownish black
DiaphaneityOpaque
Specific gravity7.8
PleochroismStrong (reflected light)
Fusibility2
Other characteristicsgarlic odor on heating
References

Small quantities of sulfur, iron and cobalt are usually present, and sometimes the arsenic is largely replaced by antimony. This last forms an isomorphous series with breithauptite (nickel antimonide).

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