Ammonium dihydrogen phosphate

Ammonium dihydrogen phosphate (ADP), also known as monoammonium phosphate (MAP) is a chemical compound with the chemical formula (NH4)(H2PO4). ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. It also has significant uses in optics and electronics.

Ammonium dihydrogen phosphate
Names
IUPAC name
Ammonium dihydrogen phosphate
Other names
Monoammonium phosphate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.028.877
EC Number
  • 231-764-5
E number E342(i) (antioxidants, ...)
UNII
  • InChI=1S/H3N.H3O4P/c;1-5(2,3)4/h1H3;(H3,1,2,3,4) Y
    Key: LFVGISIMTYGQHF-UHFFFAOYSA-N Y
  • InChI=1/H3N.H3O4P/c;1-5(2,3)4/h1H3;(H3,1,2,3,4)
    Key: LFVGISIMTYGQHF-UHFFFAOYAX
  • [O-]P(=O)(O)O.[NH4+]
Properties
H6NO4P
Molar mass 115.025 g·mol−1
Appearance white crystals
Odor none
Density 1.80 g/cm3
Melting point 190 °C (374 °F; 463 K)
(g/dL) 28 (10 °C)
36 (20 °C)
44 (30 °C)
56 (40 °C)
66 (50 °C)
81 (60 °C)
99 (70 °C)
118 (80 °C)
173 (100 °C)
Solubility insoluble in ethanol
insoluble in acetone
1.525
Structure
tetragonal
Thermochemistry
−1445.07 kJ/mol
Hazards
GHS labelling:
Warning
H319
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
1
0
0
Lethal dose or concentration (LD, LC):
5750 mg/kg (rat, oral)
Related compounds
Other anions
Ammonium phosphate
Diammonium phosphate
Other cations
Monosodium phosphate
Potassium dihydrogen phosphate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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