Melanterite

Melanterite is a mineral form of hydrous iron(II) sulfate: FeSO4·7H2O. It is the iron analogue of the copper sulfate chalcanthite. It alters to siderotil by loss of water. It is a secondary sulfate mineral which forms from the oxidation of primary sulfide minerals such as pyrite and marcasite in the near-surface environment. It often occurs as a post mine encrustation on old underground mine surfaces. It also occurs in coal and lignite seams exposed to humid air and as a rare sublimate phase around volcanic fumaroles. Associated minerals include pisanite, chalcanthite, epsomite, pickeringite, halotrichite and other sulfate minerals.

Melanterite
Melanterite as found in nature
General
CategorySulfate mineral
Formula
(repeating unit)
FeSO4·7H2O
IMA symbolMln
Strunz classification7.CB.35
Dana classification29.06.10.01
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/c
Unit cella = 14.077 Å, b = 6.509 Å,
c = 11.054 Å; β = 105.6°; Z = 4
Identification
ColorGreen, pale green, greenish blue, bluish green, colorless
Crystal habitEncrustations and capillary efflorescences; rarely as equant pseudo-octahedral, prismatic or tabular crystals
Cleavage{001} Perfect, {110} Distinct
FractureConchoidal
Mohs scale hardness2
LusterVitreous
StreakWhite
DiaphaneitySubtransparent to translucent
Specific gravity1.89 – 1.9
Optical propertiesBiaxial (+)
Refractive indexnα = 1.470 – 1.471 nβ = 1.477 – 1.480 nγ = 1.486
References

It was first described in 1850.

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