Maleic anhydride

Maleic anhydride is an organic compound with the formula C2H2(CO)2O. It is the acid anhydride of maleic acid. It is a colorless or white solid with an acrid odor. It is produced industrially on a large scale for applications in coatings and polymers.

Maleic anhydride
Names
Preferred IUPAC name
Furan-2,5-dione
Other names
Maleic anhydride
cis-Butenedioic anhydride
2,5-Furanedione
Maleic acid anhydride
Toxilic anhydride
Identifiers
3D model (JSmol)
106909
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.003.247
EC Number
  • 203-571-6
2728
RTECS number
  • ON3675000
UNII
UN number 2215
  • InChI=1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H Y
    Key: FPYJFEHAWHCUMM-UHFFFAOYSA-N Y
  • InChI=1/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
    Key: FPYJFEHAWHCUMM-UHFFFAOYAP
  • C1=CC(=O)OC1=O
Properties
C4H2O3
Molar mass 98.057 g·mol−1
Appearance White crystals or needles
Odor irritating, choking
Density 1.48 g/cm3
Melting point 52.8 °C (127.0 °F; 325.9 K)
Boiling point 202 °C (396 °F; 475 K)
Reacts
Vapor pressure 0.2 mmHg (20°C)
-35.8·10−6 cm3/mol
Hazards
GHS labelling:
Danger
H302, H314, H317, H334, H372
P260, P261, P264, P270, P272, P280, P285, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P310, P314, P321, P330, P333+P313, P342+P311, P363, P405, P501
NFPA 704 (fire diamond)
3
1
1
Flash point 102 °C (216 °F; 375 K)
Explosive limits 1.4%-7.1%
Lethal dose or concentration (LD, LC):
465 mg/kg (oral, mouse)
850 mg/kg (oral, rat)
875 mg/kg (oral, rabbit)
390 mg/kg (oral, guinea pig)
400 mg/kg (oral, rat)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (0.25 ppm)
REL (Recommended)
TWA 1 mg/m3 (0.25 ppm)
IDLH (Immediate danger)
10 mg/m3
Safety data sheet (SDS) MSDS at J. T. Baker
Related compounds
Succinic anhydride
Related compounds
Maleic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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