Lithium iodate

Lithium iodate (LiIO3) is a negative uniaxial crystal for nonlinear, acousto-optical and piezoelectric applications. It has been utilized for 347 nm ruby lasers.

Lithium iodate
Names
IUPAC name
Lithium iodate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.954
EC Number
  • 237-365-2
UNII
UN number 1479
  • InChI=1S/HIO3.Li/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 Y
    Key: FZAXZVHFYFGNBX-UHFFFAOYSA-M Y
  • [Li+].[O-]I(=O)=O
Properties
LiIO3
Appearance White hygroscopic crystals
Odor Odorless
Density 4.487 g/cm3
Melting point 420–450 °C (788–842 °F; 693–723 K)
Anhydrous:
89.4 g/100 mL (10 °C)
82.7 g/100 mL (25 °C)
78.4 g/100 mL (40.1 °C)
73 g/100 mL (75.6 °C)
Hemihydrate:
80.2 g/100 mL (18 °C)
Solubility Insoluble in EtOH
47.0·10−6 cm3/mol
Thermal conductivity 1.27 W/m·K (a-axis)
0.65 W/m·K (c-axis)
1.8875 (20 °C)
1.6 (RT)
nHe–Ne:
1.8815 (20 °C)
1.5928 (RT)
Structure
Hexagonal, hP10
P6322, No. 182
622
a = 5.46(9) Å, c = 5.15(5) Å
α = 90°, β = 90°, γ = 120°
Hazards
GHS labelling:
Danger
H272, H315, H319, H335, H360
P201, P220, P261, P305+P351+P338, P308+P313
NFPA 704 (fire diamond)
2
0
2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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