Lithium carbonate

Lithium carbonate is an inorganic compound, the lithium salt of carbonic acid with the formula Li
2
CO
3
. This white salt is widely used in processing metal oxides. It is on the World Health Organization's List of Essential Medicines for its efficacy in the treatment of mood disorders such as bipolar disorder.

Lithium carbonate
Names
IUPAC name
Lithium carbonate
Other names
Dilithium carbonate, Carbolith, Cibalith-S, Duralith, Eskalith, Lithane, Lithizine, Lithobid, Lithonate, Lithotabs Priadel, Zabuyelite
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.008.239
KEGG
RTECS number
  • OJ5800000
UNII
  • InChI=1S/CH2O3.2Li/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 Y
    Key: XGZVUEUWXADBQD-UHFFFAOYSA-L Y
  • InChI=1/CH2O3.2Li/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
    Key: XGZVUEUWXADBQD-NUQVWONBAY
  • [Li+].[Li+].[O-]C([O-])=O
Properties
Li
2
CO
3
Molar mass 73.89 g/mol
Appearance Odorless white powder
Density 2.11 g/cm3
Melting point 723 °C (1,333 °F; 996 K)
Boiling point 1,310 °C (2,390 °F; 1,580 K)
Decomposes from ~1300 °C
  • 1.54 g/100mL (0 °C)
  • 1.43 g/100mL (10 °C)
  • 1.29 g/100mL (25 °C)
  • 1.08 g/100mL (40 °C)
  • 0.69 g/100mL (100 °C)
8.15×104
Solubility Insoluble in acetone, ammonia, alcohol
−27.0·10−6 cm3/mol
1.428
Viscosity
  • 4.64 cP (777 °C)
  • 3.36 cP (817 °C)
Thermochemistry
97.4 J/mol·K
90.37 J/mol·K
−1215.6 kJ/mol
−1132.4 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant
GHS labelling:
Warning
H302, H319
P305+P351+P338
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
525 mg/kg (oral, rat)
Safety data sheet (SDS) ICSC 1109
Related compounds
Other cations
Sodium carbonate
Potassium carbonate
Rubidium carbonate
Caesium carbonate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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