Tetraethyllead

Tetraethyllead
Names
Preferred IUPAC name
Tetraethylplumbane
Other names
Lead tetraethyl

Tetraethyl lead

Tetra-ethyl lead
Identifiers
3D model (JSmol)
Abbreviations TEL
3903146
ChEBI
ChemSpider
ECHA InfoCard 100.000.979
EC Number
  • 201-075-4
68951
MeSH Tetraethyl+lead
RTECS number
  • TP4550000
UNII
UN number 1649
  • InChI=1S/4C2H5.Pb/c4*1-2;/h4*1H2,2H3; Y
    Key: MRMOZBOQVYRSEM-UHFFFAOYSA-N Y
  • CC[Pb](CC)(CC)CC
Properties
C8H20Pb
Molar mass 323.4 g·mol−1
Appearance Colorless liquid
Odor pleasant, sweet
Density 1.653 g cm−3
Melting point −136 °C (−213 °F; 137 K)
Boiling point 84 to 85 °C (183 to 185 °F; 357 to 358 K) 15 mmHg
200 parts per billion (ppb) (20 °C)
Vapor pressure 0.2 mmHg (20 °C)
1.5198
Structure
Tetrahedral
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable, extremely toxic
GHS labelling:
H300+H310+H330, H360, H373, H410
P201, P202, P260, P262, P264, P270, P271, P273, P280, P281, P284, P301+P310, P302+P350, P304+P340, P308+P313, P310, P314, P320, P321, P322, P330, P361, P363, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
4
2
3
Flash point 73 °C (163 °F; 346 K)
Explosive limits 1.8%–?
Lethal dose or concentration (LD, LC):
35 mg/kg (rat, oral)
17 mg/kg (rat, oral)
12.3 mg/kg (rat, oral)
30 mg/kg (rabbit, oral)
24 mg/kg (rat, oral)
850 mg/m3 (rat, 1 hr)
650 mg/m3 (mouse, 7 hr)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.075 mg/m3 [skin]
REL (Recommended)
TWA 0.075 mg/m3 [skin]
IDLH (Immediate danger)
40 mg/m3 (as Pb)
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)
Infobox references

Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb(C2H5)4. It is a fuel additive, first being mixed with gasoline beginning in the 1920s as a patented octane rating booster that allowed engine compression to be raised substantially. This in turn increased vehicle performance and fuel economy. TEL was first synthesised by German chemist Carl Jacob Löwig in 1853. American chemical engineer Thomas Midgley Jr., who was working for General Motors, was the first to discover its effectiveness as an antiknock agent in 1921, after spending several years attempting to find an additive that was both highly effective and inexpensive.

Concerns were later raised over the toxic effects of lead, especially on children. On cars not designed to operate on leaded gasoline, lead and lead oxides coat the catalyst in catalytic converters, rendering them ineffective, and can sometimes foul spark plugs. Starting in the 1970s, many countries began phasing out TEL in automotive fuel. In 2011 a study, backed by the United Nations, estimated that the removal of TEL had resulted in $2.4 trillion in annual benefits, and 1.2 million fewer premature deaths.

TEL is still used as an additive in some grades of aviation fuel. Innospec has claimed to be the last firm legally making TEL but, as of 2013, TEL was being produced illegally by several companies in China. In July 2021, the sale of leaded gasoline for cars was completely phased out worldwide, prompting the United Nations Environment Programme (UNEP) to declare an "official end" of its use in cars on August 30, 2021.

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