Iron phosphide

Iron phosphide is a chemical compound of iron and phosphorus, with a formula of FeP. Its physical appearance is grey, hexagonal needles.

Iron phosphide
Identifiers
3D model (JSmol)
  • InChI=1S/3Fe.H3P/h;;;1H3
  • [Fe]12[Fe]3[Fe]1P23
Properties
FeP
Molar mass 86.819 g·mol−1
Density 6.74 g/cm3
Melting point 1,100 °C (2,010 °F; 1,370 K)
Insoluble in water
Solubility soluble in nitric acid, HF, aqua regia
insoluble in dilute acid, alkalis
Structure
MnP type (Orthorhombic)
Pnma (No. 62)
a = 519.1 pm, b = 309.9 pm, c = 579.2 pm
Related compounds
Other cations
Chromium phosphide
Manganese phosphide
Cobalt phosphide
Tungsten phosphide
Ruthenium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Manufacturing of iron phosphide takes place at elevated temperatures, where the elements combine directly. Iron phosphide reacts with moisture and acids producing phosphine (PH3), a toxic and pyrophoric gas.

Iron phosphide can be used as a semiconductor. It has use in high power, high frequency applications, such as laser diodes.

Below a Néel temperature of about 119 K, FeP takes on an helimagnetic structure.

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