Halloysite

Halloysite is an aluminosilicate clay mineral with the empirical formula Al2Si2O5(OH)4. Its main constituents are oxygen (55.78%), silicon (21.76%), aluminium (20.90%), and hydrogen (1.56%). It is a member of the kaolinite group. Halloysite typically forms by hydrothermal alteration of alumino-silicate minerals. It can occur intermixed with dickite, kaolinite, montmorillonite and other clay minerals. X-ray diffraction studies are required for positive identification. It was first described in 1826, and subsequently named after, the Belgian geologist Omalius d'Halloy.

Halloysite
General
CategoryPhyllosilicates
Kaolinite-serpentine group
Formula
(repeating unit)
Al2Si2O5(OH)4
Strunz classification9.ED.10
Crystal systemMonoclinic
Crystal classDomatic (m)
(same H-M symbol)
Space groupCc
Unit cella = 5.14, b = 8.9,
c = 7.214 [Å]; β = 99.7°; Z = 1
Identification
ColorWhite; grey, green, blue, yellow, red from included impurities.
Crystal habitSpherical clusters, massive
CleavageProbable on {001}
FractureConchoidal
Mohs scale hardness2–2.5
LusterPearly, waxy, or dull
DiaphaneitySemitransparent
Specific gravity2–2.65
Optical propertiesBiaxial
Refractive indexnα = 1.553–1.565
nβ = 1.559–1.569
nγ = 1.560–1.570
Birefringenceδ = 0.007
References
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