Dimethoxymethane

Dimethoxymethane, also called methylal, is a colorless flammable liquid with a low boiling point, low viscosity and excellent dissolving power. It has a chloroform-like odor and a pungent taste. It is the dimethyl acetal of formaldehyde. Dimethoxymethane is soluble in three parts water and miscible with most common organic solvents.

Dimethoxymethane
Names
Preferred IUPAC name
Dimethoxymethane
Other names
Formal

Formaldehyde dimethyl ether
Methylal
Dimethylformal (DMFL)
Formaldehyde dimethylacetal
Methoxymethyl methyl ether

Methylene dimethyl ether
Identifiers
3D model (JSmol)
1697025
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.003.378
EC Number
  • 203-714-2
100776
MeSH Dimethoxymethane
RTECS number
  • PA8750000
UNII
UN number 1234
  • InChI=1S/C3H8O2/c1-4-3-5-2/h3H2,1-2H3 Y
    Key: NKDDWNXOKDWJAK-UHFFFAOYSA-N Y
  • InChI=1/C3H8O2/c1-4-3-5-2/h3H2,1-2H3
    Key: NKDDWNXOKDWJAK-UHFFFAOYAE
  • COCOC
Properties
C3H8O2
Molar mass 76.095 g·mol−1
Appearance Colorless liquid
Odor Chloroform-like
Density 0.8593 g cm−3 (at 20 °C)
Melting point −105 °C (−157 °F; 168 K)
Boiling point 42 °C (108 °F; 315 K)
33% (20 °C)
Vapor pressure 330 mmHg (20 °C)
−47.3·10−6 cm3/mol
Hazards
GHS labelling:
Danger
H225, H315, H319, H335
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, P501
Flash point −18 °C (0 °F; 255 K)
Explosive limits 2.2–13.8%
Lethal dose or concentration (LD, LC):
5708 mg/kg (rabbit, oral)
18000 ppm (mouse, 7 hr)
15000 ppm (rat)
18354 ppm (mouse, 7 hr)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1000 ppm (3100 mg/m3)
REL (Recommended)
TWA 1000 ppm (3100 mg/m3)
IDLH (Immediate danger)
2200 ppm
Related compounds
Related Ethers
Dimethoxyethane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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