Dicopper chloride trihydroxide

Dicopper chloride trihydroxide is the chemical compound with the formula Cu2(OH)3Cl. It is often referred to as tribasic copper chloride (TBCC), copper trihydroxyl chloride or copper hydroxychloride. It is a greenish crystalline solid encountered in mineral deposits, metal corrosion products, industrial products, art and archeological objects, and some living systems. It was originally manufactured on an industrial scale as a precipitated material used as either a chemical intermediate or a fungicide. Since 1994, a purified, crystallized product has been produced at the scale of thousands of tons per year, and used extensively as a nutritional supplement for animals.

Dicopper chloride trihydroxide
Names
Preferred IUPAC name
Copper trihydroxyl chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.014.158
EC Number
  • 215-572-9
UNII
  • InChI=1S/ClH.2Cu.3H2O/h1H;;;3*1H2/q;2*+2;;;/p-4
    Key: SKQUUKNCBWILCD-UHFFFAOYSA-J
  • [OH-].[OH-].[OH-].[Cl-].[Cu+2].[Cu+2]
Properties
Cu2(OH)3Cl
Molar mass 213.56
Appearance Green crystalline solid
Density 3.5 g/cm3
Melting point 250 °C; 482 °F; 523 K
Insoluble in water,
pH 6.9 measured by EPA method SW846-9045
Solubility Insoluble in organic solvents
Structure
Atacamite: orthorhombic

Paratacamite: rhombohedral

Clinoatacamite: monoclinic

Botallackite: monoclinic

Distorted octahedral
Hazards
NFPA 704 (fire diamond)
1
0
0
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)
REL (Recommended)
TWA 1 mg/m3 (as Cu)
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)
Safety data sheet (SDS)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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