Dakin oxidation
The Dakin oxidation (or Dakin reaction) is an organic redox reaction in which an ortho- or para-hydroxylated phenyl aldehyde (2-hydroxybenzaldehyde or 4-hydroxybenzaldehyde) or ketone reacts with hydrogen peroxide (H2O2) in base to form a benzenediol and a carboxylate. Overall, the carbonyl group is oxidised, whereas the H2O2 is reduced.
| Dakin reaction | |
|---|---|
| Named after | Henry Drysdale Dakin |
| Reaction type | Organic redox reaction |
| Identifiers | |
| Organic Chemistry Portal | dakin-reaction |
| RSC ontology ID | RXNO:0000169 |
The Dakin oxidation, which is closely related to the Baeyer–Villiger oxidation, is not to be confused with the Dakin–West reaction, though both are named after Henry Drysdale Dakin.
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