Scheele's Green

Scheele's Green, also called Schloss Green, is chemically a cupric hydrogen arsenite (also called copper arsenite or acidic copper arsenite), CuHAsO
3
. It is chemically related to Paris Green. Scheele's Green was invented in 1775 by Carl Wilhelm Scheele. By the end of the 19th century, it had virtually replaced the older green pigments based on copper carbonate. It is a yellowish-green pigment commonly used during the early to mid-19th century in paints as well as being directly incorporated into a variety of products as a colorant. It began to fall out of favor after the 1860s because of its toxicity and the instability of its color in the presence of sulfides and various chemical pollutants. The acutely toxic nature of Scheele's green as well as other arsenic-containing green pigments such as Paris Green may have contributed to the sharp decline in the popularity of the color green in late Victorian society. By the dawn of the 20th century, Scheele's green had completely fallen out of use as a pigment but was still in use as an insecticide into the 1930s. At least two modern reproductions of Scheele's green hue with modern non-toxic pigments have been made, with similar but non-identical color coordinates: one with hex#3c7a18 (RGB 60, 122, 24) and another with hex#478800 (RGB 71, 136, 0). The latter is the more typically reported color coordinate for Scheele's green.

Scheele's Green
Names
IUPAC name
copper hydrogen arsenite
Other names
Copper arsenite
Copper arsenate
Swedish Green
Cupric Green
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.573
  • InChI=1S/AsHO3.Cu/c2-1(3)4;/h2H;/q-2;+2 Y
    Key: BPQWCZKMOKHAJF-UHFFFAOYSA-N Y
  • InChI=1/AsHO3.Cu/c2-1(3)4;/h2H;/q-2;+2
    Key: BPQWCZKMOKHAJF-UHFFFAOYAR
  • [Cu+2].[O-][As]([O-])O
Properties
AsCuHO3
Molar mass 187.474
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
[1910.1018] TWA 0.010 mg/m3
REL (Recommended)
Ca C 0.002 mg/m3 [15-minute]
IDLH (Immediate danger)
Ca [5 mg/m3 (as As)]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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