Chromium(IV) oxide

Chromium dioxide or chromium(IV) oxide is an inorganic compound with the formula CrO2. It is a black synthetic magnetic solid. It once was widely used in magnetic tape emulsion. With the increasing popularity of CDs and DVDs, the use of chromium(IV) oxide has declined. However, it is still used in data tape applications for enterprise-class storage systems. It is still considered by many oxide and tape manufacturers to have been one of the best magnetic recording particulates ever invented.

Chromium(IV) oxide
Names
IUPAC name
Chromium(IV) oxide, Chromium dioxide
Other names
Crolyn
magtrieve
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.031.470
RTECS number
  • GB6400000
UNII
  • InChI=1S/Cr.2O Y
    Key: AYTAKQFHWFYBMA-UHFFFAOYSA-N Y
  • InChI=1/Cr.2O/rCrO2/c2-1-3
    Key: AYTAKQFHWFYBMA-QAVXBIOBAI
  • O=[Cr]=O
Properties
CrO2
Molar mass 83.9949 g/mol
Appearance black tetrahedral ferromagnetic crystals
Density 4.89 g/cm3
Melting point 375 °C (707 °F; 648 K) (decomposes)
Insoluble
Structure
Rutile (tetragonal), tP6
P42/mnm, No. 136
Hazards
Flash point Non-flammable
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3
REL (Recommended)
TWA 0.5 mg/m3
IDLH (Immediate danger)
250 mg/m3
Safety data sheet (SDS) ICSC 1310
Related compounds
Other cations
Vanadium(IV) oxide
Manganese(IV) oxide
Related
Chromium(II) oxide
Chromium(II,III) oxide
Chromium(III) oxide
Chromium trioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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