Cervandonite

Cervandonite is a rare arsenosilicate mineral. It has a chemical formula (Ce,Nd,La)(Fe3+
,Fe2+
,Ti4+
,Al)
3
SiAs(Si,As)O
13
or (Ce,Nd,La)(Fe3+
,Fe2+
,Ti,Al)
3
O
2
(Si
2
O
7
)(As3+
O
3
)(OH)
. It has a monoclinic crustal structure with supercell (Z=6), the crystal structure was established as a trigonal subcell, with space group R3m and a = 6.508(1)Ǻ, c = 18.520(3) Ǻ, V 679.4(2) Ǻ3, and Z=3. It was first described by Buhler Armbruster in 1988, but it has proven to be problem due to the extreme scarcity of single crystals and its unusual replacement of silicon and arsenic. Cervandonite is named after the location where it was first described, Pizzo Cervandone (Scherbadung), Italy in the Central Alps.

Cervandonite
Cervandonite is a classic and very sought after mineral from Binntal.
General
CategorySilicate mineral
Formula
(repeating unit)
(Ce,Nd,La)(Fe3+
,Fe2+
,Ti,Al)
3
O
2
(Si
2
O
7
)(As3+
O
3
)(OH)
Strunz classification9.BE.09.2
Crystal systemTrigonal
Space groupR3m
Identification
ColorBlack
Crystal habitAggregates and rosettes of tabular crystals
Cleavage{001} Indistinct
FractureConchoidal
TenacityBrittle
LusterAdamantine
StreakBrownish black
DiaphaneityTranslucent to opaque
Specific gravity4.9 (calculated)
Optical propertiesBiaxial
Refractive indexnα = 1.990 nγ = 2.000
PleochroismYellowish, reddish brown to black
References
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