Calcium nitrate

Calcium nitrate, also called Norgessalpeter or Norwegian salpeter, is an inorganic compound with the formula Ca(NO3)2(H2O)x. The anhydrous compound, which is rarely encountered, absorbs moisture from the air to give the tetrahydrate. Both anhydrous and hydrated forms are colourless salts. Calcium nitrate is mainly used as a component in fertilizers, but it has other applications. Nitrocalcite is the name for a mineral which is a hydrated calcium nitrate that forms as an efflorescence where manure contacts concrete or limestone in a dry environment as in stables or caverns. A variety of double salts are known including calcium ammonium nitrate decahydrate (NH4NO3·5Ca(NO3)2·10H2O) and calcium potassium nitrate (Ca(NO3)2·4KNO3).

Calcium nitrate
Names
Other names
Kalksalpeter, Norgessalpeter, nitrocalcite, Norwegian salpeter, lime nitrate
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.030.289
EC Number
  • 233-332-1
RTECS number
  • EW2985000
UNII
UN number 1454
  • InChI=1S/Ca.2NO3/c;2*2-1(3)4/q+2;2*-1 Y
    Key: ZCCIPPOKBCJFDN-UHFFFAOYSA-N Y
  • InChI=1/Ca.2NO3/c;2*2-1(3)4/q+2;2*-1
    Key: ZCCIPPOKBCJFDN-UHFFFAOYAF
  • [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Ca(NO3)2
Molar mass 164.088 g/mol (anhydrous)
236.15 g/mol (tetrahydrate)
Appearance colorless solid
hygroscopic
Density 2.504 g/cm3 (anhydrous)
1.896 g/cm3 (tetrahydrate)
Melting point 561 °C (1,042 °F; 834 K) (anhydrous)
42.7 °C (109 °F; 316 K) (tetrahydrate)
Boiling point decomposes (anhydrous)
132 °C (270 °F; 405 K) (tetrahydrate)
anhydrous:
1212 g/L (20 °C)
2710 g/L (40 °C)
tetrahydrate:
1050 g/L (0 °C)
1290 g/L (20 °C)
3630 g/L (100 °C)
Solubility soluble in ammonia
almost insoluble in nitric acid
Solubility in ethanol 51.4 g/100 g (20 °C)
62.9 g/100 g (40 °C)
Solubility in methanol 134 g/100 g (10 °C)
144 g/100 g (40 °C)
158 g/100 g (60 °C)
Solubility in acetone 33.08 g/100g (anhydrous, 25 °C)
Acidity (pKa) 6.0
-45.9·10−6 cm3/mol
Structure
cubic (anhydrous)
monoclinic (tetrahydrate)
Hazards
GHS labelling:
Danger
H272, H302, H315, H319
P210, P220, P221, P264, P270, P280, P301+P312, P302+P352, P305+P351+P338, P310, P321, P330, P332+P313, P337+P313, P362, P370+P378, P501
NFPA 704 (fire diamond)
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
302 mg/kg (rat, oral)
Safety data sheet (SDS) ICSC 1037
Related compounds
Other anions
Calcium sulfate
Calcium chloride
Other cations
Magnesium nitrate
Strontium nitrate
Barium nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references
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