Boron trichloride
Boron trichloride is the inorganic compound with the formula BCl3. This colorless gas is a reagent in organic synthesis. It is highly reactive toward water.
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Names | |||
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IUPAC name
Boron trichloride | |||
Other names
Boron(III) chloride Trichloroborane | |||
Identifiers | |||
3D model (JSmol) |
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ChemSpider | |||
ECHA InfoCard | 100.030.586 | ||
EC Number |
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PubChem CID |
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RTECS number |
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UNII | |||
CompTox Dashboard (EPA) |
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Properties | |||
BCl3 | |||
Molar mass | 117.17 g/mol | ||
Appearance | Colorless gas, fumes in air | ||
Density | 1.326 g/cm3 | ||
Melting point | −107.3 °C (−161.1 °F; 165.8 K) | ||
Boiling point | 12.6 °C (54.7 °F; 285.8 K) | ||
hydrolysis | |||
Solubility | soluble in CCl4, ethanol | ||
-59.9·10−6 cm3/mol | |||
Refractive index (nD) |
1.00139 | ||
Structure | |||
Trigonal planar (D3h) | |||
zero | |||
Thermochemistry | |||
Heat capacity (C) |
107 J/mol K | ||
Std molar entropy (S⦵298) |
206 J/mol K | ||
Std enthalpy of formation (ΔfH⦵298) |
-427 kJ/mol | ||
Gibbs free energy (ΔfG⦵) |
-387.2 kJ/mol | ||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards |
May be fatal if swallowed or if inhaled Causes serious burns to eyes, skin, mouth, lungs, etc. Contact with water gives HCl | ||
GHS labelling: | |||
Danger | |||
H300, H314, H330 | |||
NFPA 704 (fire diamond) | |||
Flash point | Non-flammable | ||
Safety data sheet (SDS) | ICSC | ||
Related compounds | |||
Other anions |
Boron trifluoride Boron tribromide Boron triiodide | ||
Other cations |
Aluminium trichloride Gallium trichloride | ||
Related compounds |
Boron trioxide Carbon tetrachloride | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
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